Critical chloride content: realistic determination and application in practice
Responsible: Deniz Yilmaz
Collaborations: ASTRA, Norwegian Public Roads Administration, ASFINAG

Background
The concept of the critical chloride content has been used since the 1950s to define a threshold value above which corrosion of steel in concrete occurs. Unfortunately, as reviewed in a external page comprehensive study, the reported literature value scatter widely and provide a poor basis for engineering practice, where input values for service life predictions are needed. A major drawback of the vast majority of laboratory studies can be found in the difficulties to mimic, in laboratory made samples, practice-related conditions at the steel-concrete interface.
Aims and objectives
This project aims to determine the critical chloride content by testing samples taken from engineering structures, rather than laboratory made samples. The aim is to deliver a database of the statistical distribution of critical chloride contents in a range of typical Swiss engineering structures.
Methodology
Reinforced concrete cores are drilled from a number of different engineering structures (not yet corroding). These samples are then tested in the laboratory with a recently developed method. Detailed descriptions of this published “ETH-protocol” can be found external page here.
After corrosion initiation, the samples are split and the steel-concrete interface carefully inspected in order to gain insight in to the influence on corrosion initiation.

Online resources
All results of this study are systematically collected in an open access database on critical chloride contents.
The database and the related descriptions can be accessed here:
• Link to Ccrit Database (continuously updated)
• Link to external page documentation and external page explanations related to the database
If you wish to explore the database you may wish to visit the online interactive visualization of the collected data at the following webpage: Critical chloride visualization
Publications
- Die objektspezifische Bestimmung des kritischen Chloridgehalts und die Auswirkung auf die Restlebensdauer
Carolina Boschmann Käthler and Ueli M. Angst
4. Brückenkolloquium, TAE, Esslingen: September 2020 - The critical chloride content - determination at structures and the influence on service life
Carolina Boschmann Käthler and Ueli M. Angst
Bautechnik, vol. 97: no. 1, pp. 41-47, Berlin: Wiley, 2020
external page DOI: 10.1002/bate.201900089 - A novel approach to systematically collect critical chloride contents in concrete in an open access data base
Carolina Boschmann Käthler, Ueli Angst, Asel M. Aguilar Sanchez and Bernhard Elsener
Data in Brief, vol. 27, pp. 104675, Amsterdam: Elsevier, 2019
external page DOI: 10.1016/j.dib.2019.104675
- A database of critical chloride contents for fundamental understanding of corrosion initiation and service life modelling
Carolina Boschmann Käthler, Ueli M. Angst, and Bernhard Elsener
Proceedings of EUROCORR 2019: New times, new materials, new corrosion challenges, pp. 192501, S.l.: European Corrosion Congress, 2019 - external page A systematic data collection on chloride-induced steel corrosion in concrete to improve service life modelling and towards understanding corrosion initiation
Carolina Boschmann Käthler, Ueli Angst, Asel Maria Aguilar Sanchez, and Bernhard Elsener
Corrosion Science, vol. 157: no. 331, pp. 336, Orlando, FL: Elsevier, 2019
external page DOI: 10.1016/j.corsci.2019.06.008 - Towards understanding corrosion initiation in concrete-influence of local concrete properties in the steel-concrete interfacial zone
Carolina Boschmann Käthler, Ueli M. Angst, and Bernhard Elsener
5th International Conference on Concrete Repair, Rehabilitation and Retrofitting (ICCRRR 2018), Cape Town, South Africa, pp.04002 Les Ulis: EDP Sciences, November 19-21,2018
external page DOI: 10.1051/matecconf/201819904002 - Measuring critical chloride contents in structures and the influence on service life modeling
Carolina Boschmann Käthler, Ueli Angst, and Bernhard Elsener
6th International Symposium on Life-Cycle Civil Engineering (IALCCE 2018), Ghent, Belgium, pp.973-978, London: CRC Press/Balkema, October 28-31, 2018 - Image analysis for determination of cement content in concrete to improve accuracy of chloride analyses
Carolina Boschmann Käthler, Ueli M. Angst, Matthias Wagner, and Bernhard Elsener Cement and Concrete Research, vol. 99, pp. 1-7, Amsterdam: Elsevier, 2017.
external page DOI: 10.1016/j.cemconres.2017.04.007 - Experimental Protocol to Determine the Chloride Threshold Value for Corrosion in Samples Taken from Reinforced Concrete Structures
Ueli M. Angst, Carolina Boschmann, Matthias Wagner, and Bernhard Elsener
Journal of Visualized Experiments. JoVE, vol. 126, pp. e56229, Somerville, MA: JoVE, 2017.
external page DOI: 10.3791/56229